
The chemistry of icy giant planets such as Neptune and Uranus has recently attracted the attention of the scientific community. The mantle of these planets is mainly composed of a dense fluid mixture of water, methane and ammonia. The extreme pressure and temperature conditions (T>1000 K, and P>3 GPa) in icy giants involve complex reactions that dictate many of the chemical and physical properties of these planets. In this regard, the formation of diamonds and super-ionic water (diamond rain) from planetary mixtures has been invoked to rationalize the luminosity and anisotropic magnetic field of icy giants. CHEMRAIN aims to break the borders to the so far inaccessible extreme chemistry of icy giants' interior. CHEMRAIN will simulate for the first time the early stages of nanodiamond nucleation from a fluid mixture representative of the interior of icy giants. Our main objective is to understand the chemistry under extreme conditions of diamond nucleation at the nanoscale. This will be achieved by developing a protocol gathering an array of state of-the-art computational techniques : ab initio methods, molecular dynamics, enhanced sampling techniques (metadynamics, umbrella sampling), QM:QM multi embedded scheme, theoretical spectroscopy and topological electronic descriptors (e.g. electron localization functions (ELF) ). The combination of enhanced sampling techniques and ab initio molecular dynamics will allow for the exploration of the reactivity of the planetary mixture, overcoming current time limitations in modelling diamond formation. This will lead to the discovery of realistic transformation mechanisms and free energy barriers for nanodiamond nucleation in planetary mixtures, taking into account the effects of pressure, temperature, and solvation. In the second step, the application of ELF on the reactive species along the transition pathway, obtained by reactive molecular dynamics, will allow for the study of how the nature of the binding network, charges, and volume of the binding and non-binding doublets evolve during the nucleation of nano-diamonds. This will open the way for a complete identification of the nature of the chemical environment (molecular, ionic, superionic, etc.) at icy giant P,T conditions, shedding light on the effect of extreme conditions on the reactivity of planetary mixtures. Finally, CHEMRAIN will establish a connection between experiments and simulations through vibrational theoretical spectroscopy. The modeling of new phases of planetary mixtures, including diamond and super ionic H2O, in addition to theoretical spectroscopy will bridge the gap between the nature of planetary mixtures probed in Raman high-pressure experiments and in simulations.
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</script>The subject of study of differential geometry are smooth manifolds, which correspond to smooth curved objects of finite dimension. In modern differential geometry, it is becoming more and more common to consider sequences (or flows) of smooth manifolds. Typically the limits of such sequences (or flows) are non smooth anymore. It is then useful to isolate a natural class of non smooth objects which generalize the classical notion of smooth manifold, and which is closed under the process of taking limits. If the sequence of manifolds satisfy a lower bound on the sectional curvatures, a natural class of non-smooth objects which is closed under (Gromov-Hausdorff) convergence is given by special metric spaces known as Alexandrov spaces; if instead the sequence of manifolds satisfy a lower bound on the Ricci curvatures, a natural class of non-smooth objects, closed under (measured Gromov-Hausdorff) convergence, is given by special metric measure spaces (i.e. metric spaces endowed with a reference volume measure) known as RCD(K,N) spaces. These are a 'Riemannian' refinement of the so called CD(K,N) spaces of Lott-Sturm-Villani, which are metric measure spaces with Ricci curvature bounded below by K and dimension bounded above by N in a synthetic sense via optimal transport. In the proposed project we aim to understand in more detail the structure, the analytic and the geometric properties of RCD(K,N) spaces. The new results will have an impact also on the classical world of smooth manifolds satisfying curvature bounds.
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</script>Hyperelliptic curves are a fundamental class of polynomial equations that has featured in geometry and number theory for a very long time, but whose arithmetic has not yet been subject to a systematic study. This gap in our knowledge is rapidly becoming apparent, as demands for the theory are coming both from within pure mathematics, from areas bordering to theoretical physics (via the new theory of hypergeometric motives), and from cryptography, where one of the main methods for modern data encryption is based on hyperelliptic curves. The purpose of the project is to modernise our approach to the arithmetic of hyperelliptic curves, by bringing in the number theoretic machinery of L-functions and Selmer groups into the subject. These are tools that have been the centre of attention of many number theorists over the past few decades, and lie at the heart of the works on Fermat's Last Theorem, the Langlands programme and the Birch-Swinnerton-Dyer conjecture. They promise to provide new theoretical and computational techniques for working with hyperelliptic curves, and our aim is to establish foundational results whose analogues have been central to the development of other parts of number theory. From the point of view of the established theory of L-functions, the step into hyperelliptic curves is partly a step into unchartered territory, for hyperelliptic curves cannot be treated by the comfortably familiar techniques based on modular forms. We thus plan to expand and test the L-function theory beyond its standard boundaries, and hope to shed light on the many unresolved conjectures in the subject. The interplay of hyperelliptic curves, L-functions and Selmer groups is the rationale for proposing a single unified project. Our aim is to produce mathematical results, algorithms and data that can be used in each of these three worlds. Apart from establishing results for number theorists, we aim to explore phenomena and develop concrete classifications and a database, that would also be accessible to scientists from other fields working with hyperelliptic curves.
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</script>This School will review the state of the art in the theory and experiment on quantum nano-systems and nano-structured materials. The course will cover the following topics: (i) electronic properties of the recently discovered new 2D material - graphene, review of the recent progress in quantum Hall effect and spin-Hall effect; (ii) carbon nanotubes, Luttinger liquid in quantum wires and the bosonisation technique, Kondo effect, functional renormalisation group methods; (iii) quantum information processing, phase coherence and de-coherence in qubits, coherent exciton dynamics and optical properties of quantum dots and microcavities, adiabatic and non-adiabatic dynamics of quantum condensates of finite dimensions. The lectures in theoretical methods will be complemented by reviews of advanced experiments and focused research seminars. The lectures and the seminars will be delivered by leading specialists from the USA, the UK, Germany, etc (a full list is in the case for support).
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