
The data have been partially published in PANGAEA before (Aromokeye, D A et al., 2018), but with core depth, not sediment depths.Methods:Bulk elemental composition: Dissolution of dry sediment in a mixture of 65% HNO3 (3 ml), 30% HCl (2 ml), and 40% suprapur® HF (0.5 ml) in a CEM Mars Xpress microwave system. Elemental contents determined by ICP-OES (Inductively coupled plasma – optical emission spectroscopy; Iris Intrepid II).Sequential Fe extraction after Poulton and Canfield (2005) and Henkel et al. (2016). Fe aca (1 M Na-acetate, 24 h, pH 4.5); Fe hyam (1 M hydroxylamine-HCl in 25% v/v acetic acid, 48 h); Fe di-ct (Na-dithionite (50 g L-1)/0.02 M Na-citrate, 2 h, pH 4.8); Fe oxa (0.2 M ammonium oxalate/0.17 M oxalic acid, 6 h). Iron contents determined by ICP-OES (Inductively coupled plasma – optical emission spectroscopy; Iris Intrepid II ICP-OES)
Solid-phase samples were collected onboard (RV Heincke expedition HE443) using cut-off syringes. The MUC was sliced and sampled. For sampling the GC, small windows were drilled into the liner through which the syringes were introduced. All samples were stored anoxically and frozen at -20°C until processing. The processing involved freeze-drying and grinding before splitting the samples for the different kinds of analyses.
Depth, corrected, CHSN Elemental Analyser, inorganic, Thermo Electron, Hot extraction using 6 M HCl and trapping of extracted S as Ag2S, Iron, hydroxylamine-HCl-leached, ELTRA, Iris Intrepid II, Chromium reducible iron (pyrite), Germany, stable iron isotopes, Aluminium, Magnesium, total, Center for Marine Environmental Sciences (MARUM), MultiCorer, Titanium, Sequential Fe extraction (Poulton & Canfield, 2005; Henkel et al., 2016), vario EL III, 2005 Henkel et al, Inductively coupled plasma optical emission spectrometer ICP OES, Iron in pyrite, sequential iron extractions, Phosphorus, HE443, dithionite citrate leached, hydroxylamine HCl leached, Iron in acid volatile sulfides, sediment rock, Iron, dithionite-citrate-leached, Iron, reactive, Barium, Iron, acetate-leached, Nitrogen, total, Heincke, Inductively coupled plasma-optical emission spectrometer (ICP-OES), Thermo Electron, Iris Intrepid II, Earth System Research, Sequential Fe extraction Poulton Canfield, acetate leached, North Sea, Elementar Analysen systeme GmbH, Nitrogen, 2016, organic, Carbon, total, Iron, pore water, Carbon, inorganic, total, DEPTH, sediment/rock, Helgoland mud area, Carbon Sulfur analyzer, Acid volatile sulfides, CS 2000, Center for Marine Environmental Sciences MARUM, Sequential Fe extraction (Poulton & Canfield, 2005; Henkel et al., 2016), Manganese, Depth, Event label, Hot extraction using and a chromous chloride solution and trapping of extracted S as Ag2S, Carbon, Carbon-Sulfur analyzer, ELTRA, CS-2000, sediment, oxalate leached, Strontium, DEPTH, Potassium, corrected, reactive, Calcium, Gravity corer, CHSN Elemental Analyser, Elementar Analysen systeme GmbH, Germany, vario EL III, Chromium reducible iron pyrite, Sulfur, Carbon, organic, total, Iron, oxalate-leached
Depth, corrected, CHSN Elemental Analyser, inorganic, Thermo Electron, Hot extraction using 6 M HCl and trapping of extracted S as Ag2S, Iron, hydroxylamine-HCl-leached, ELTRA, Iris Intrepid II, Chromium reducible iron (pyrite), Germany, stable iron isotopes, Aluminium, Magnesium, total, Center for Marine Environmental Sciences (MARUM), MultiCorer, Titanium, Sequential Fe extraction (Poulton & Canfield, 2005; Henkel et al., 2016), vario EL III, 2005 Henkel et al, Inductively coupled plasma optical emission spectrometer ICP OES, Iron in pyrite, sequential iron extractions, Phosphorus, HE443, dithionite citrate leached, hydroxylamine HCl leached, Iron in acid volatile sulfides, sediment rock, Iron, dithionite-citrate-leached, Iron, reactive, Barium, Iron, acetate-leached, Nitrogen, total, Heincke, Inductively coupled plasma-optical emission spectrometer (ICP-OES), Thermo Electron, Iris Intrepid II, Earth System Research, Sequential Fe extraction Poulton Canfield, acetate leached, North Sea, Elementar Analysen systeme GmbH, Nitrogen, 2016, organic, Carbon, total, Iron, pore water, Carbon, inorganic, total, DEPTH, sediment/rock, Helgoland mud area, Carbon Sulfur analyzer, Acid volatile sulfides, CS 2000, Center for Marine Environmental Sciences MARUM, Sequential Fe extraction (Poulton & Canfield, 2005; Henkel et al., 2016), Manganese, Depth, Event label, Hot extraction using and a chromous chloride solution and trapping of extracted S as Ag2S, Carbon, Carbon-Sulfur analyzer, ELTRA, CS-2000, sediment, oxalate leached, Strontium, DEPTH, Potassium, corrected, reactive, Calcium, Gravity corer, CHSN Elemental Analyser, Elementar Analysen systeme GmbH, Germany, vario EL III, Chromium reducible iron pyrite, Sulfur, Carbon, organic, total, Iron, oxalate-leached
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