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Physical Review B
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Physical Review B
Article . 2004 . Peer-reviewed
License: APS Licenses for Journal Article Re-use
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Enhanced ferroelectric phase-transition temperature in perovskite-based solid solutions

Authors: V. A. Stephanovich; M. D. Glinchuk; C. A. Randall;

Enhanced ferroelectric phase-transition temperature in perovskite-based solid solutions

Abstract

We explain how the phenomena of ferroelectric phase transition temperature ${T}_{c}$ enhancement beyond the end members in perovskite solid solution such as $\mathrm{Bi}M{\mathrm{O}}_{3}\text{\ensuremath{-}}{\mathrm{PbTiO}}_{3}$ ($M=\mathrm{Sc}$, In, etc.) is related to nonlinear and spatial correlation effects. The explanation is based on the calculation of ${T}_{c}$ in the framework of our random field theory with additional account for nonlinear effects in the above substances. We show that the maximum of ${T}_{c}$ for certain ${\mathrm{PbTiO}}_{3}$ content takes place when coefficient of nonlinearity is positive, the value of this coefficient is found from best fit between theory and experiment. This nonlinearity coefficient is the only adjustable parameter of the theory. We show that enhancement of positive nonlinearity coefficients enhances greatly the ${T}_{c}$ maximum over its value for end members.The theory lays the foundation to calculate not only ${T}_{c}$ for above solid solutions but virtually any equilibrium and/or nonequilibrium thermodynamic characteristics such as static and dynamic dielectric susceptibility, specific heat, etc., as a function of ${\mathrm{PbTiO}}_{3}$ content, temperature, electric field, and other external parameters.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
6
Average
Top 10%
Top 10%
bronze
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