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Vapour-Liquid Equilibria in the Poly(methyl methacrylate) ++2-Butanone System Containing Lower Concentrations of Solute at Normal or Reduced Pressures
Vapour-Liquid Equilibria in the Poly(methyl methacrylate) ++2-Butanone System Containing Lower Concentrations of Solute at Normal or Reduced Pressures
Vapour–liquid equilibria (VLE) were determined in the poly(methyl methacrylate) + 2-butanone system under isothermal conditions at 333.15, 343.15, and 353.15 K using an improved all-glass microebulliometer with circulation of the liquid phase for the dynamic measurement of total pressure over liquid mixtures. The experimental data were correlated using the UNIQUAC model. The Entropic-FV and the GC-Flory equation of state models were applied to predict VLE, and the results were compared with the experimental data. Both predictive models proved of the same quality and capable of predicting VLE for the studied system.
- Czech Academy of Sciences Czech Republic
- Academy of Sciences Library Czech Republic
- Academy of Sciences of the Czech Republic Czech Republic
- Academy of Science of the Czech Republic Czech Republic
Microsoft Academic Graph classification: Isothermal process Equation of state UNIQUAC Total pressure Ebulliometer Chromatography Thermodynamics Poly(methyl methacrylate) visual_art.visual_art_medium visual_art Methyl methacrylate chemistry.chemical_compound chemistry 2-butanone
vapor-liquid equilibria; poly(methyl methacrylate); 2-butanone; experimental; prediction, vapour–liquid equilibrium; experimental data; polymer–solvent system; correlation; ebulliometer, vapor-liquid equilibrium, ebulliometer, experimental data, Process Chemistry and Technology, General Chemistry, Biochemistry
vapor-liquid equilibria; poly(methyl methacrylate); 2-butanone; experimental; prediction, vapour–liquid equilibrium; experimental data; polymer–solvent system; correlation; ebulliometer, vapor-liquid equilibrium, ebulliometer, experimental data, Process Chemistry and Technology, General Chemistry, Biochemistry
Microsoft Academic Graph classification: Isothermal process Equation of state UNIQUAC Total pressure Ebulliometer Chromatography Thermodynamics Poly(methyl methacrylate) visual_art.visual_art_medium visual_art Methyl methacrylate chemistry.chemical_compound chemistry 2-butanone
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2. Pavlíček, J., Bogdanić, G., Wichterle, I., Circulation micro-ebulliometer for determination of pressure above mixtures containing solvent and non-volatile component, Fluid Phase Equilib. 297 (2010) 142. http://dx.doi.org/10.1016/j.fluid.2010.05.022
3. Bogdanić, G., Wichterle, I., Vapor−liquid equilibrium in diluted polymer + solvent systems, J. Chem. Eng. Data 56 (2011) 1080. http://dx.doi.org/10.1021/je101052a [OpenAIRE]
4. Jonquières, A., Perrin, L., Arnold, S., Lochon, P., Comparison of UNIQUAC with related models for modelling vapour sorption in polar materials, J. Membrane Sci. 150 (1998) 125. http://dx.doi.org/10.1016/S0376-7388(98)00221-X [OpenAIRE]
5. Kontogeorgis, G. M., Folas, G. K., Thermodynamic Models for Industrial Applications: From Classical and Advanced Mixing Rules to Association Theories, Wiley, Chichester, 2010. http://dx.doi.org/10.1002/9780470747537
6. Daubert, T. E., Danner, R. P., Data Compilation Tables of Properties of Pure Compounds, Design Institute for Physical Property Data, American Institute of Chemical Engineers (DIPPR/AIChE), 1993.
7. Rodgers, P. A., Pressure-volume-temperature relationships for polymeric liquids: A review of equations of state and their characteristic parameters for 56 polymers, J. Appl. Polym. Sci. 48 (1993) 1061. http://dx.doi.org/10.1002/app.1993.070480613
8. Bondi, A., Physical Properties of Macromolecular Crystals, Liquid and Glasses, Wiley, New York, 1968.
9. Tait, P. J. T., Abushihada, A. M., Comparative studies on the use of gas chromatographic and vapour pressure techniques for the determination of the interaction energy parameter, Polymer 18 (1977) 810. http://dx.doi.org/10.1016/0032-3861(77)90186-0
10. Wang, K., Xue, Q., Hu, Y., Study on the vapour-liquid equilibria of the mixtures of 2-butanone-PMMA and chloroform-PMMA system, Huadong Ligong Daxue Xuebao (J. East China Univ. Sci. Technol.) 23 (1997) 109. (in Chinese)
11. Regener, E., Wohlfarth, Ch., Rätzsch, M. T., Höring, S., Thermodynamik konzentrierter Poly(methylmethacrylat)- -Lösungen, Acta Polym. 39 (1988) 618. http://dx.doi.org/10.1002/actp.1988.010391105
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- Czech Academy of Sciences Czech Republic
- Academy of Sciences Library Czech Republic
- Academy of Sciences of the Czech Republic Czech Republic
- Academy of Science of the Czech Republic Czech Republic
Vapour–liquid equilibria (VLE) were determined in the poly(methyl methacrylate) + 2-butanone system under isothermal conditions at 333.15, 343.15, and 353.15 K using an improved all-glass microebulliometer with circulation of the liquid phase for the dynamic measurement of total pressure over liquid mixtures. The experimental data were correlated using the UNIQUAC model. The Entropic-FV and the GC-Flory equation of state models were applied to predict VLE, and the results were compared with the experimental data. Both predictive models proved of the same quality and capable of predicting VLE for the studied system.