publication . Article . 2017

Polyacrylamide-lithium chloride polymer electrolyte and its applications in electrochemical capacitors

Keryn Lian; Alvin Virya;
Open Access
  • Published: 01 Jan 2017 Journal: Electrochemistry Communications, volume 74, pages 33-37 (issn: 1388-2481, Copyright policy)
  • Publisher: Elsevier BV
Abstract
A neutral polymer electrolyte containing lithium chloride (LiCl) and polyacrylamide (PAM) was developed. The LiCl-PAM electrolyte film had an amorphous structure and an ionic conductivity > 10 mS cm−1. The addition of LiCl to the polyacrylamide did not alter the chemical bonding of PAM. Symmetric double layer capacitors (EDLC) were constructed using CNT-graphite electrodes. The solid EDLC retained approximately 85% of the capacitance achieved with a baseline cell in a LiCl aqueous solution. The solid EDLC devices demonstrated a wide voltage window (1.5 V), good cycle life (>10,000 cycles), and excellent rate capability (up to 5 V s−1). Keywords: Solid supercapac...
Subjects
free text keywords: Industrial electrochemistry, TP250-261, Chemistry, QD1-999
Funded by
NSERC
Project
  • Funder: Natural Sciences and Engineering Research Council of Canada (NSERC)
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