publication . Other literature type . Article . 1996

PREFER : a new layered (alumino) silicate precursor of FER-type zeolite

L. Schreyeck; Bernd Marler; J.C. Mougenel; Philippe Caullet; Jean-Louis Guth;
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  • Published: 01 Jul 1996
  • Publisher: Elsevier BV
Abstract
Abstract A new layered microporous (alumino) silicate showing (100) ferrierite layers and called PREFER was synthesised from fluoride-containing aqueous media in the presence of a novel bulky template, the 4-amino-2,2,6,6-tetramethyl-piperidine. Calcination at about 500°C of this ‘as-made’ product leads to FER-type zeolite by a transformation occurring through the intermediate formation of poorly organised phases. The whole set of results obtained by several techniques such as variable-temperature XRD, chemical and thermal analyses and 29Si MAS NMR spectroscopy are consistent with a 2D→3D transformation process. Indeed, during the calcination, the (100) ferrieri...
Subjects
free text keywords: General Engineering, General Materials Science, General Chemistry, Inorganic chemistry, Calcination, law.invention, law, Chemistry, Silicate, chemistry.chemical_compound, Chemical engineering, Aluminosilicate, Ferrierite, Silicon, chemistry.chemical_element, Zeolite, Molecular sieve, Microporous material
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