Photoionization dynamics of bounded electrons in the ground state, the first and second excited states of a hydrogen atom, triggered by ultrashort near-infrared laser pulses, have been investigated in a transition regime (γ∼1) that offers both multiphoton and tunneling features. Significant differences in spectral characteristics are found between the three low-energy states. The H(2s) ionization probability is larger than the H(2p) value with a special oscillating structure, but both are much greater than the ground state H(1s) in a wide range of laser intensities. By comparing the momentum spectrum and angular distributions of low-energy photoelectrons released from these degenerate states, we find the H(2p) state shows a stronger long-range Coulomb attraction force than the H(2s) state on account of the difference in the initial electron wave packet. Furthermore, analysis of the photoelectron momentum distributions sheds light on both the first and second excited states with a symmetrical intercycle interference structure in a multicycle field but an intracycle interference of an asymmetric left-handed or right-handed rotating spectrum in a few-cycle field. By analyzing photoelectron spectroscopy, we identify the parity characteristics of photoelectrons in different energy intervals and their corresponding above-threshold single-photon ionization (ATSI) or above-threshold double-photon ionization (ATDI) processes. We finally present the momentum distributions of the electrons ionized by laser pulses with different profiles and find the carrier-envelope phase (CEP) is a strong factor in deciding the rotating structure of the emission spectrum, which provides a new method to distinguish the CEP of few-cycle pulses.