
Abstract This paper describes the development of acidizing systems that use several different aldehyde-based sulfide suppression chemicals in conjunction with new acid corrosion inhibitors. Specific combinations of these chemicals have allowed the acid to dissolve FeS, suppress H2S and still enable the acid to be inhibited to industry corrosion standards. Laboratory tests include dissolution of FeS, measurement of H2S evolved, measurement of acid concentration and chloride ion concentrations. We also determined the effect of FeS and H2S on the corrosion of oilfield steels with these additives. Laboratory measurements covered the temperature range from 75 to 275 °F (reservoir temperature). Experimental results were compared with that previously published data.1 The new system enabled the acid to dissolve more FeS than fluids containing previously tested suppressors, while controlling H2S evolution and corrosion. During field testing, samples of the spent acid were captured and were analyzed for [Fe], [S2−] and [HCl]. The data will contribute to an understanding of the corrosion processes and sulfide control during acid treatments. The field acid treatments were accomplished successfully without significant changes in procedures and resulted in large increase in gas production. This system is designed primarily for "tube cleaning" operations prior to acid stimulation (matrix and fracture acidizing), but the control chemicals have also been tested for use in the actual stimulation fluid stages. The new chemicals and procedures will allow the operators to safely remove large amounts of fouling deposits, while controlling the toxic and corrosive effects of H2S much more effectively than previously used products.
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