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Kemija u Industriji
Article . 2022
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Anode Development of Carbon Paste/NP by Cobalt Deposition for Direct Ethanol Application

Sakina Touzara; Olivier Francois Aristide Bertrand Koffi; Abdelilah Chtaini;

Anode Development of Carbon Paste/NP by Cobalt Deposition for Direct Ethanol Application

Abstract

Cilj ovog rada bio je ispitati elektrolitičku oksidaciju etanola u alkalnoj otopini pomoću elektrode od ugljikove paste modificirane prirodnim fosfatom i kobaltom (Co-NP/CPE). Elektrode su dobivene elektrodepozicijom kobalta na ugljik-NP supstrat, primjenom potenciostatskih i galvanostatskih tehnika. Morfološka karakterizacija modificiranih elektroda provedena je optičkom mikroskopijom koja je pokazala dobru raspršenost kobalta te prisutnost NP čestica na površini elektrode. Usporedbom dobivenih voltamograma vidljivo je da navedena elektroda pokazuje katalitički učinak što dovodi do bolje oksidacije etanola. U usporedbi s nemodificiranom CPE-NP elektrodom, elektroda modificirana kobaltom pokazuje visoku elektrolitičku aktivnost za oksidaciju etanola. Ovo djelo je dano na korištenje pod licencom Creative Commons Imenovanje 4.0 međunarodna.

This work aims to study the electrolytic oxidation of ethanol in alkaline solution by a carbon paste electrode modified with natural phosphate and cobalt (Co-NP/CPE). The electrodes were obtained by depositing the cobalt on carbon-NP substrates by electrodeposition, using potentiostatic and galvanostatic techniques. Morphological characterisation by optical microscopy techniques shows that the Co is well dispersed with the presence of NP particles on the surface of the electrode. The study of the electrode behaviour by voltammetric techniques exhibits a catalytic effect leading to a better result regarding the oxidation of ethanol. Compared to CPE-NP, the cobalt-modified CPE-NP electrode exhibits high electrolytic activity for ethanol oxidation. This work is licensed under a Creative Commons Attribution 4.0 International License.

Country
Croatia
Keywords

electro-deposition; cobalt; cyclic voltammetry; oxidation of ethanol; natural phosphate, elektrodepozicija; kobalt; ciklička voltametrija; oksidacija etanola; prirodni fosfat, General Chemical Engineering, General Chemistry

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This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
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influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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