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Diffusion coefficients of cerate solutions

Authors: McFadden, Mary Louise;

Diffusion coefficients of cerate solutions

Abstract

The apparent integral diffusion coefficients of ceric sulphate solutions, 4 normal in sulphuric acid, were measured for concentrations ranging from 0.05 normal to 0.415 normal at 25°C with the use of a pyrex sintered glass diaphragm diffusion cell. A graph obtained by plotting the calculated integral diffusion coefficients versus the square root of the initial concentration is similar to the graphs obtained for uni-univalent salts. The rate of diffusion, however, is less by a factor of ten. The sintered glass diaphragm cell was calibrated with 0.1 normal potassium chloride at 25°C and the value of the cell constant was determined to be 0.1111 ± 0.0002 cm⁻².

Keywords

Diffusion

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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