Catalysis by Heteropolyacid. V. Catalytic Alkylation of Toluene by Mixed-coordination type, H4[SiMo12−nWnO40], Heteropolyacid

descriptionPublicationkeyboard_double_arrow_right Article 01 Dec 1980 English Publisher:Oxford University Press (OUP)Journal:Bulletin of the Chemical Society of Japan, volume 53, pages 3,719-3,720 (issn: 0009-2673, eissn: 1348-0634,

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Authors: Kenji Nomiya; Hidehiko Saijoh; Makoto Miwa;

doi: 10.1246/bcsj.53.3719

Catalysis by Heteropolyacid. V. Catalytic Alkylation of Toluene by Mixed-coordination type, H4[SiMo12−nWnO40], Heteropolyacid

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Abstract

Abstract To compare the specific difference between molybdenum and tungsten ions on the catalytic reaction, we investigated the alkylation of toluene with benzyl chloride by mixed-metal heteropolyacids, H4[SiMo12−nWnO40] (n=0, 1, 10, and 11). Molybdenum-rich compound is more active than tungsten-rich one.

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Seikei University
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