publication . Article . 2015

Structure and spectroscopic properties of , -coordinating 2-methylsulfanyl- -[(1 -pyrrol-2-yl)methylidene]aniline methanol monosolvate

Richards, D. Douglas; Ang, M. Trisha C.; McDonald, Robert; Bierenstiel, Matthias;
Open Access
  • Published: 12 Sep 2015
  • Publisher: (:unav)
The reaction of pyrrole-2-carboxaldehyde and 2-(methylsulfanyl)aniline in refluxing methanol gave an olive-green residue in which yellow crystals of the title compound, C H N S·CH OH, were grown from slow evaporation of methanol at 263 K. In the crystal, hydrogen-bonding interactions link the aniline molecule and a nearby methanol solvent molecule. These units are linked by a pair of weak C—H...O interactions, forming inversion dimers consisting of two main molecules and two solvent molecules.
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free text keywords: Condensed Matter Physics, General Materials Science, General Chemistry, Aniline, chemistry.chemical_compound, chemistry, Imine, Hydrogen bond, Methanol, Sulfanyl, Solvent, Schiff base, Organic chemistry, Medicinal chemistry, Crystal structure
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