
pmid: 10033927
We observed soliton shape modes by photoinduced absorption in partially isomerized ${(\mathrm{CH})}_{x}$ and ${(\mathrm{CD})}_{x}$, coexisting with the soliton translational modes. The shape modes' ir activity, their dependence on the degree of isomerization, and the photoinduced spectra are explained in detail by a symmetry-breaking interaction which allows coupling of shape modes and translational modes. We also observed soliton shape-mode absorption in fully isomerized samples as phonon sidebands associated with optical transitions of neutral solitons above 1.5 eV.
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