Uranyl-Tc(  vii  )/Tc(  v  ) hybrid clusters

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2024 English Publisher:Royal Society of Chemistry (RSC)Journal:Chemical Communications, volume 60, pages 5,820-5,823 (issn: 1359-7345, eissn: 1364-548X,

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Authors: Mohammad Shohel; May Nyman;

doi: 10.1039/d4cc01726a

pmid: 38747178

Uranyl-Tc( vii )/Tc( v ) hybrid clusters

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Abstract

Pertechnetate ( 99 Tc VII O 4 − ) and autoreduced 99 Tc( v ), species coordinate to UO 2 2+ to form hybrid clusters. These clusters have important implications to understanding technetium chemistry in spent nuclear fuel and legacy wastes.

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