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Ir I (η 4 -diene) precatalyst activation by strong bases: formation of an anionic Ir III tetrahydride

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2023 France Publisher:Royal Society of Chemistry (RSC)Journal:Dalton Transactions, volume 52, pages 2,495-2,505 (issn: 1477-9226, eissn: 1477-9234,

Authors: Paven Kisten; Eric Manoury; Agustí Lledós; Adrian C. Whitwood; Jason M. Lynam; John M. Slattery; Simon B. Duckett; +1 Authors

doi: 10.1039/d2dt04036k

pmid: 36727834

Ir I (η 4 -diene) precatalyst activation by strong bases: formation of an anionic Ir III tetrahydride

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Abstract

Complex [IrCl(COD)(dppe)] yields [IrH4(dppe)]− at 80 °C (or at room T under H2) in the presence of strong base and isopropanol, hinting to the nature the active species in Ir-catalysed hydrogenations and transfer hydrogenations.

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France

Related Organizations

Autonomous University of Barcelona
Spain
University of Toulouse
France
French National Centre for Scientific Research
France
Laboratoire Parole et Langage
France
University of York
United Kingdom

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Keywords

[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistry, [CHIM.COOR]Chemical Sciences/Coordination chemistry, [CHIM.CATA]Chemical Sciences/Catalysis

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ラットにおけるDoxapram hydrochlorideの代謝物に関する研究
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СОПОЛИМЕРЫ ВИНИЛХЛОРИДА И 1-ВИНИЛ-4,5,6,7-ТЕТРАГИДРОИНДОЛА
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	citations This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).	0
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