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Conducting chiral nickel(ii) bis(dithiolene) complexes: structural and electron transport modulation with the charge and the number of stereogenic centres

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2021 Spain, France English Publisher:Royal Society of Chemistry (RSC)Journal:Journal of Materials Chemistry C, volume 9, pages 4,119-4,140 (issn: 2050-7526, eissn: 2050-7534,

Authors: Abhervé, Alexandre; Mroweh, Nabil; Cauchy, Thomas; Pop, Flavia; Cui, Hengbo; Kato, Reizo; Vanthuyne, Nicolas; +3 Authors

doi: 10.1039/d1tc00439e

handle: 10261/237533 , 2445/184769

Conducting chiral nickel(ii) bis(dithiolene) complexes: structural and electron transport modulation with the charge and the number of stereogenic centres

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Abstract

Chiral nickel(ii) bis(dithiolene) complexes based on the mono- and bis-methylated ligands me-dddt and dm-dddt are Mott insulators or band gap semiconductors, with their conductivity modulated by the counter-ion and the number of stereogenic centres.

Countries

Spain, France

Related Organizations

Laboratoire Parole et Langage
France
University of Barcelona
Spain
RIKEN
Japan
Institut des Sciences Moléculaires de Marseille
France
Aix-Marseille University
France

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Keywords

Anions, Direct band gap semiconductors, Intermolecular interactions, Níquel, Electron transport, Conducting properties, Antiferromagnetic ground state, Band structure calculation, Conducting materials, Molecular materials, Nickel, Quiralitat, [CHIM] Chemical Sciences, Chirality

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