Stereochemistry of the reduction of 24-methyldesmosterol to campesterol and dihydrobrassicasterol in higher plants

Y. Fujimoto; N. Sato; K. Iwai; H. Hamada; J. Yamada; M. Morisaki

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Chemical Communicati...arrow_drop_down

Chemical Communications

Article . 1997 . Peer-reviewed

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https://dx.doi.org/10.1039/a70...

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Stereochemistry of the reduction of 24-methyldesmosterol to campesterol and dihydrobrassicasterol in higher plants

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1997 Japan Publisher:Royal Society of Chemistry (RSC)Journal:Chemical Communications (issn: 1359-7345, eissn: 1364-548X,

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Authors: Y. Fujimoto; N. Sato; K. Iwai; H. Hamada; J. Yamada; M. Morisaki;

doi: 10.1039/a700492c

Stereochemistry of the reduction of 24-methyldesmosterol to campesterol and dihydrobrassicasterol in higher plants

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Abstract

Feeding of chemically synthesized [26- 13 C]- and [27- 13 C]-labelled 24-methyldesmosterols to tissue cultures of Oryza satiba and Catharanthus roseus followed by 13 C NMR analysis of the biosynthesized sterols reveals that reduction of the 24(25)-double bond giving either campesterol or dihydrobrassicasterol takes place in an anti-manner.

Country

Japan

Related Organizations

Institute of Science Tokyo
Japan

Keywords

570, 572

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