Relation between Thermodynamic Property Change and Vibrational Frequency Shift in Ethyl Halides

descriptionPublicationkeyboard_double_arrow_right Article 13 Aug 1966 English Publisher:Springer Science and Business Media LLCJournal:Nature, volume 211, pages 742-742 (issn: 0028-0836, eissn: 1476-4687,

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Authors: J. LIELMEZS;

doi: 10.1038/211742a0

Relation between Thermodynamic Property Change and Vibrational Frequency Shift in Ethyl Halides

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Abstract

RELATIONS can be found by plotting the difference of the ideal gas state thermodynamic properties ΔS° and ΔCp°; formed between the thermodynamic property values of ethane, C2H6, and its homologues, C2H5X (X = F, Cl, Br, I), against the corresponding C–X bond stretching and C–C–X bond bending frequencies in ethyl halide series (Fig. 1). The results are presented in Table 1.

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