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Journal of Geophysical Research Atmospheres
Article . 2001 . Peer-reviewed
License: Wiley Online Library User Agreement
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Isotopic composition of stratospheric water vapor: Implications for transport

Authors: David G. Johnson; Kenneth W. Jucks; Wesley A. Traub; Kelly V. Chance;

Isotopic composition of stratospheric water vapor: Implications for transport

Abstract

We develop a series of models of transport in the upper tropical troposphere in order to explain the observed abundance and isotopic composition of stratospheric water vapor. We start with the Rayleigh fractionation process and add the effects of mixing and recirculation of stratospheric air through the upper troposphere. We compare our measurements with model calculations for a range of input parameters and find that the observations are best explained by a model that mixes vapor from roughly 11 km (carried aloft either as condensate or through radiative heating and uplift) with air that has been dehydrated (in a large convective system) to a mixing ratio substantially below the saturation mixing ratio of the mean tropical tropopause. The result is that while most of the moisture comes from convective outflow near 11 km, most of the air in the upper troposphere consists of dehydrated air from convective systems with cloud top temperatures below that of the mean tropical tropopause. We also find that the water vapor mixing ratio in the stratosphere is determined not only by the temperature of the tropical tropopause but also by the relative importance of radiative heating, recirculation of stratospheric air, and deep convection in supplying air to the upper troposphere. Our results show that water vapor isotope ratios are a powerful diagnostic tool for testing the results of general circulation models.

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    popularity
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    influence
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
45
Top 10%
Top 10%
Top 10%
bronze