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Publication . Article . 2012

Efficient Amine End-Functionalization of Living Ring-Opening Metathesis Polymers

Nagarkar, Amit A.; Crochet, Aurélien; Fromm, Katharina M.; Kilbinger, Andreas F. M.;
Open Access  
Published: 10 Jul 2012
Publisher: American Chemical Society (ACS)
Country: Switzerland
Abstract
An efficient strategy for the synthesis of monoamine end-functionalized living polymers using ring-opening metathesis polymerization with ruthenium initiators is reported. A new end-capping agent for this purpose was synthesized, and its efficiency for end-functionalization was evaluated using two common ruthenium-based initiators. Finally, terminal cross-metathesis was also explored as another alternative toward the synthesis of amine end-functionalized polymers, and the comparison between the two techniques is presented.
Subjects by Vocabulary

Microsoft Academic Graph classification: Ruthenium chemistry.chemical_element chemistry Surface modification Polymerization Amine gas treating Polymer chemistry Ring (chemistry) Polymer chemistry.chemical_classification Metathesis

Subjects

Materials Chemistry, Inorganic Chemistry, Polymers and Plastics, Organic Chemistry