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Macromolecules; ZENODO
Article . 2012 . Peer-reviewed
License: CC BY
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Macromolecules
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License: CC BY
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Efficient amine end-functionalization of living ring-Opening metathesis polymers

Authors: Amit A. Nagarkar; Aurelien Crochet; Katharina M. Fromm; Andreas F.M. Kilbinger;

Efficient amine end-functionalization of living ring-Opening metathesis polymers

Abstract

An efficient strategy for the synthesis of monoamine end-functionalized living polymers using ring-opening metathesis polymerization with ruthenium initiators is reported. A new end-capping agent for this purpose was synthesized, and its efficiency for end-functionalization was evaluated using two common ruthenium-based initiators. Finally, terminal cross-metathesis was also explored as another alternative toward the synthesis of amine end-functionalized polymers, and the comparison between the two techniques is presented.

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Switzerland
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    Impact byBIP!
    citations
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    51
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 10%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Top 10%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 10%
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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
51
Top 10%
Top 10%
Top 10%
Green
hybrid