publication . Article . 2009

Mechanism of C−P Reductive Elimination from trans-[Pd(CH═CHPh)Br(PMePh2)2]

Masayuki Wakioka; Yumiko Nakajima; Fumiyuki Ozawa;
  • Published: 23 Mar 2009 Journal: Organometallics, volume 28, pages 2,527-2,534 (issn: 0276-7333, eissn: 1520-6041, Copyright policy)
  • Publisher: American Chemical Society (ACS)
Abstract
The (E)- and (Z)-styryl isomers of trans-[Pd(CH═CHPh)Br(PMePh2)2] (1a) and [Pd(η2-PhCH═CHPMePh2)Br(PMePh2)] (2a) were prepared, and their C−P reductive elimination (1a → 2a) and C−P oxidative addit...
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free text keywords: Inorganic Chemistry, Organic Chemistry, Physical and Theoretical Chemistry, Chemistry, Reductive elimination, Medicinal chemistry
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