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Photodissociation Dynamics of Phenol

descriptionPublicationkeyboard_double_arrow_right Article 10 Aug 2007Publisher:American Chemical Society (ACS)Journal:The Journal of Physical Chemistry A, volume 111, pages 9,463-9,470 (issn: 1089-5639, eissn: 1520-5215,

Authors: Yuan-Pern Lee; Chien-Ming Tseng; Suet Yi Liu; Z. F. Xu; Ming-Chang Lin; Chi-Kung Ni; Yuan T. Lee; +1 Authors

doi: 10.1021/jp073282z

pmid: 17691716

Photodissociation Dynamics of Phenol

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Abstract

The photodissociation of phenol at 193 and 248 nm was studied using multimass ion-imaging techniques and step-scan time-resolved Fourier-transform spectroscopy. The major dissociation channels at 193 nm include cleavage of the OH bond, elimination of CO, and elimination of H(2)O. Only the former two channels are observed at 248 nm. The translational energy distribution shows that H-atom elimination occurs in both the electronically excited and ground states, but elimination of CO or H(2)O occurs in the electronic ground state. Rotationally resolved emission spectra of CO (1

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