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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
Chemical Engineering Journal
Article . 2016 . Peer-reviewed
License: Elsevier TDM
Data sources: Crossref
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What’s wrong with Lagergreen pseudo first order model for adsorption kinetics?

Authors: Rodrigues, Alirio E.; Silva, Carlos Manuel;

What’s wrong with Lagergreen pseudo first order model for adsorption kinetics?

Abstract

Abstract Adsorption processes can be modeled on the basis of phenomenological principles using conservation, equilibrium and transport kinetics equations. However many times an empirical approach is followed using pseudo first order and pseudo second order models to describe adsorption kinetics. In this short communication we discuss the use of Lagergreen model (pseudo first order kinetic model) and compare it with the linear driving force model of Glueckauf for a linear adsorption equilibrium isotherm. A relation between the kinetic constants of both models is derived, being possible to disclose they exhibit very distinct dependency with temperature whatever the porous structure of the adsorbent particle. In conclusion, care must be taken when using the short-cut approach of pseudo first order expressions, taking into account their theoretically inconsistent trends.

Country
Portugal
Keywords

Kinetics, Linear system, Mass transfer, Adsorption, Glueckauf model, Lagergreen model, DRIVING-FORCE MODEL

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Powered by OpenAIRE graph
Found an issue? Give us feedback
selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
159
Top 1%
Top 10%
Top 1%
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