Characterization of hydroxyl-terminated polybutadiene

descriptionPublicationkeyboard_double_arrow_right Article 01 Mar 1997 English Publisher:Springer Science and Business Media LLCJournal:Polymer Bulletin, volume 38, pages 311-318 (issn: 0170-0839, eissn: 1436-2449,

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Authors: W. D. Vilar; S. M. C. Menezes; P. R. Seidl;

doi: 10.1007/s002890050053

Characterization of hydroxyl-terminated polybutadiene

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Abstract

1 H and 13 C NMR spectra were used to study the structure of hydroxyl-terminated polybutadiene (HTPB) obtained by using hydrogen peroxide as initiator and an alcohol as solvent. This alcohol was introduced into the polymer chain, forming a hydroxylated end group. The subject has aroused some argument in the literature and is considered further in our discussion of reaction mechanisms.

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Federal University of Rio de Janeiro
Brazil
Military Institute of Engineering
Brazil

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