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The European Physical Journal E
Article . 2000 . Peer-reviewed
License: Springer TDM
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https://dx.doi.org/10.48550/ar...
Article . 2000
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Stretching necklaces

Authors: Vilgis, T.A.; Johner, A.; Joanny, J.-F.;

Stretching necklaces

Abstract

Polyelectrolytes in poor solvents show a necklace structure where collapsed polymer pearls are linked to stretched strings. In the present paper the elasticity of such chains is studied in detail. Different deformation regimes are addressed. The first is the continuous regime, where many pearls are present. A continuous force extension relation ship is calculated. The main contribution comes from the tension balance and the electrostatic repulsion of consecutive pearls. The main correction term stems from the finite size of the pearls, which monitors their surface energy. For a finite amount of pearls discontinuous stretching is predicted. Finally counterion effects are discussed qualitatively.

to appear in European Phys. Journal E (soft matter)

Country
France
Keywords

Condensed Matter - Materials Science, Soft Condensed Matter (cond-mat.soft), Materials Science (cond-mat.mtrl-sci), FOS: Physical sciences, Condensed Matter - Soft Condensed Matter, [PHYS] Physics [physics]

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    popularity
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    influence
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
34
Average
Top 10%
Top 10%
Green