Determination of heats of aluminothermic redox reaction of V2O5 and MnO2

descriptionPublicationkeyboard_double_arrow_right Article 01 Feb 1995 English Publisher:Springer Science and Business Media LLCJournal:Journal of Thermal Analysis and Calorimetry, volume 44, pages 441-451 (issn: 0368-4466, eissn: 1572-8943,

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Authors: B. Sarangi; H. S. Ray; K. K. Tripathy; A. Sarangi;

doi: 10.1007/bf02636134

Determination of heats of aluminothermic redox reaction of V2O5 and MnO2

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Abstract

Differential thermal analysis has been used for quantitative determination of heats of aluminothermic redox reaction of MnO2 and V2O5 over a wide range of temperatures. Heat of reaction V2O5−Al and MnO2−Al systems have been determined using the calibration plot established. The experimentally determined values compare well with those predicted from thermodynamic data available in the literature. It has been found that V2O5−Al system involves a higher heat of reaction in comparison to the MnO2−Al system.

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