Application of the Prigogine-Flory-Patterson theory part I. Mixtures ofn-alkanes with bicyclic compounds, benzene, cyclohexane andn-hexane

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1989 English Publisher:Springer Science and Business Media LLCJournal:Journal of Solution Chemistry, volume 18, pages 65-80 (issn: 0095-9782, eissn: 1572-8927,

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Authors: T. M. Letcher; R. C. Baxter;

doi: 10.1007/bf00646083

Application of the Prigogine-Flory-Patterson theory part I. Mixtures ofn-alkanes with bicyclic compounds, benzene, cyclohexane andn-hexane

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Abstract

The Prigogine-Flory-Patterson theory of liquid mixtures has been applied to the HmE and VmE for binary mixtures of an n-alkane with decalin, bicyclohexyl, tetralin, cyclohexylbenzene, benzene, cyclohexane and n-hexane. Furthermore the Prigogine-Flory theory has been used to predict activity coefficients at infinite dilution from the experimentally determined HmE at 25°C and at finite concentrations for n-hexane and n-heptane with decalin, bicyclohexyl, tetralin and cyclohexylbenzene.

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