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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
Journal of Applied Electrochemistry
Article . 1994 . Peer-reviewed
License: Springer TDM
Data sources: Crossref
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Mathematical modelling of electrode growth

Authors: Deconinck, Johan;

Mathematical modelling of electrode growth

Abstract

It is known that during electrodeposition or dissolution electrode shape change depends on the local current density (Faraday's law in differential form). Assuming that concentration gradients in the bulk of the solution may be neglected, the current distribution in an electrochemical system can be modelled by a Laplace equation (describing charge transport) with nonlinear boundary conditions caused by activation and concentration overpotentials on the electrodes. To solve this numerical problem, an Euler scheme is used for the integration of Faraday's law with respect to time and the field equation is discretized using the boundary element method (BEM). In this way, and by means of a specially developed electrode growth algorithm, it is possible to simulate electrodeposition or electrode dissolution. In particular, attention is paid to electrode variation in the vicinity of singularities. It is pointed out that the angle of incidence between an electrode and an adjacent insulator becomes right (π/2). This is confirmed by several experiments.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
19
Top 10%
Top 10%
Average
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