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ZENODO; Journal of Polymer Science Part A Polymer Chemistry
Article . 2017 . Peer-reviewed
License: CC BY
Data sources: ZENODO; Crossref
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Enolesters as chain end‐functionalizing agents for the living ring opening metathesis polymerization

Authors: Peng Liu; Mohammad Yasir; Helena Kurzen; Nils Hanik; Mark Schäfer; Andreas F.M. Kilbinger;

Enolesters as chain end‐functionalizing agents for the living ring opening metathesis polymerization

Abstract

ABSTRACTFunctional enolethers have previously been used to introduce functional end groups at the chain end of ruthenium carbene complex initiated living ring opening metathesis polymers. Here, we investigated whether the weaker π‐donating enolesters could equally be used in regio selective reactions with ruthenium carbene complexes and thus as polymer end‐functionalization reagents. Enolesters such as vinyl acetate, butenyl acetate, 3‐(4‐(tert‐butoxy)phenyl)propenyl acetate and 6‐(((benzyloxy)carbonyl)amino)hex‐1‐en‐1‐yl acetate were used as living ROMP terminating agents. All gave the expected end groups proving that enolesters are synthetically easily accessible targets for living ROMP end‐functionalization. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017, 55, 2983–2990

Country
Switzerland
Subjects by Vocabulary

Microsoft Academic Graph classification: Propenyl chemistry.chemical_element ROMP Ring (chemistry) Metathesis Ruthenium chemistry.chemical_compound chemistry Polymer chemistry Vinyl acetate Ring-opening metathesis polymerisation Carbene

Keywords

Polymers and Plastics, Organic Chemistry, Materials Chemistry

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
views
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downloads
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13
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