AbstractA new open‐chain monoterpene glycoside, anatolioside E (1), was isolated from the leaves of Viburnum orientale in addition to three known acyclic monoterpene glycosides, betulalbusides A (2) and B (3), and 2(E)‐2,6‐dimethyl‐2,7‐octadien‐1,6‐diol‐6‐O‐β‐D‐glucopyranoside(4). The structure of anatolioside E (1) was elucidated on the basis of chemical and spectral data as 6‐O‐[β‐D‐glucopyransoyl‐(1‴‴ → 6‴″)‐2‐(E), 6(R), 2,6‐dimethyl‐6‐hydroxy‐2,7‐octadienoyl‐(1‴″ → 2″″)‐β‐D‐glucopyranosyl‐(1″″ → 6‴)‐2‐(E), 6(R), 2,6‐dimethyl‐6‐hydroxy‐2,7‐octadienoyl‐(1‴ → 4″)‐α‐L‐rhamnopyranosyl‐(1″″ → 2′)‐β‐D‐glucopyranosyl]linalool.