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handle: 20.500.12210/62044
AbstractCyanosilylation, aldol coupling and asymmetric Henry reactions were carried out with L‐ and D‐valmet ligands in different configurations: i) coordinated to sodium ions, as organocatalysts, with week base properties, ii) complexes with copper(II), as homogeneous catalysts, and iii) immobilized copper(II) complexes onto graphene oxide (GO) as heterogeneous catalysts. For the reaction of benzaldehyde and nitromethane in water these afforded an asymmetric Henry reaction, with a spectacular increase of the conversion and ee (92.5 and 95.8 %, respectively) after the deposition on GO. Ligand complexed copper was also effective for cyanosilylation and Aldol coupling reaction.
Cyanosilylation, L- and D-valmet ligands, [CHIM.ORGA]Chemical Sciences/Organic chemistry, Cu-complex, [CHIM.CATA]Chemical Sciences/Catalysis, 540, Immobilization, Aldol reaction;Cu-complex;Cyanosilylation;Immobilization;Henry reaction;L- and D-valmet ligands, Aldol reaction, [CHIM.COOR]Chemical Sciences/Coordination chemistry, Henry reaction
Cyanosilylation, L- and D-valmet ligands, [CHIM.ORGA]Chemical Sciences/Organic chemistry, Cu-complex, [CHIM.CATA]Chemical Sciences/Catalysis, 540, Immobilization, Aldol reaction;Cu-complex;Cyanosilylation;Immobilization;Henry reaction;L- and D-valmet ligands, Aldol reaction, [CHIM.COOR]Chemical Sciences/Coordination chemistry, Henry reaction
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