ТЕРМОДИНАМИЧЕСКАЯ МОДЕЛЬ ГАЗОВЫХ ГИДРАТОВ

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Недоступ, В. И. ; Недоступ, О. В. (2015)
  • Publisher: ООО "Институт низкотемпературных энерготехнологий"
  • Journal: Industrial Gases (issn: 1682-0355, eissn: 1682-0355)
  • Subject: Газовые гидраты; Редкие газы; Метан; Вода; Потенциальная функция; Энтальпия; Энергия; Теплота; Фазовый переход | Gas hydrates; Rare gases; Methane; Water; Potential function; Enthalpy; Ener-gy; Heat; Phase transition
    arxiv: Quantitative Biology::Biomolecules | Physics::Chemical Physics | Physics::Biological Physics

The interest to gas hydrates grows last years. Therefore working out of reliable settlement-theoretical methods of definition of their properties is necessary. The thermodynamic model of gas hydrates in which the central place occupies a behaviour of guest molecule in cell is described. The equations of interaction of molecule hydrate formative gas with cell are received, and also an enthalpy and energy of output of molecule from a cell are determined. The equation for calculation of thermodynamic characteristics of hydrate on curve  of hydrate formative is developed.
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