publication . Article . 2019

SSZ-27: A Small-Pore Zeolite with Large Heart-Shaped Cavities Determined by Using Multi-crystal Electron Diffraction

Smeets, Stef; Zones, Stacey I.; Xie, Dan; Palatinus, Lukáš; Pascual, Jesus; Hwang, Son‐Jong; Schmidt, Joel E.; McCusker, Lynne B.;
Open Access
  • Published: 09 Sep 2019
  • Publisher: Wiley
Abstract
The high‐silica zeolite SSZ‐27 was synthesized using one of the isomers of the organic structure‐directing agent that is known to produce the large‐pore zeolite SSZ‐26 (CON). The structure of the as‐synthesized form was solved using multi‐crystal electron diffraction data. Data were collected on eighteen crystals, and to obtain a high‐quality and complete data set for structure refinement, hierarchical cluster analysis was employed to select the data sets most suitable for merging. The framework structure of SSZ‐27 can be described as a combination of two types of cavities, one of which is shaped like a heart. The cavities are connected through shared 8‐ring win...
Subjects
free text keywords: General Chemistry, Catalysis, Research Article, Research Articles, Zeolites, electron diffraction, SSZ-27, structure determination, structure-directing agents (SDAs), zeolites; electron diffraction; SSZ-27; structure determination; structure-directing agents (SDAs), General Medicine, multicrystal electron diffraction, structure refinement, zeolites, SSZ-27, hierarchical cluster analysis, heart shaped cavity, Communication channel, Materials science, Zeolite, Electron diffraction, Complete data, Crystal, Molecular physics, Hierarchical clustering, Merge (version control), Data set
Communities
  • Social Science and Humanities
Funded by
NSF| Acquisition of Solid-State NMR Equipment
Project
  • Funder: National Science Foundation (NSF)
  • Project Code: 9724240
  • Funding stream: Directorate for Mathematical & Physical Sciences | Division of Materials Research
,
SNSF| Development of serial electron crystallography methodology for quantitative phase analysis
Project
  • Funder: Swiss National Science Foundation (SNSF)
  • Project Code: P300P2_177761
  • Funding stream: Careers;Fellowships | Advanced Postdoc.Mobility
,
SNSF| Development of serial crystallography methods for structure solution of polycrystalline materials using electron diffraction
Project
  • Funder: Swiss National Science Foundation (SNSF)
  • Project Code: P2EZP2_165282
  • Funding stream: Careers;Fellowships | Early Postdoc.Mobility
Download fromView all 8 versions
Open Access
NARCIS
Article . 2019
Provider: NARCIS
Open Access
Angewandte Chemie
Article . 2019
Provider: Crossref
Open Access
Caltech Authors
Article . 2019
36 references, page 1 of 3

1 S. I.Zones, Microporous Mesoporous Mater.2011, 144, 1–8.

2 F.Gao, J. H.Kwak, J.Szanyi, C. H. F.Peden, Top. Catal.2013, 56, 1441–1459.

3 C.Baerlocher, L. B.McCusker, D. H.Olson, Atlas of Zeolite Framework Types, Elsevier, Amsterdam, 2007.

4 S. I.Zones, M. M.Olmstead, D. S.Santilli, J. Am. Chem. Soc.1992, 114, 4195–4201.

5 S. I.Zones, Microporous Mater.1994, 2, 281–287.

6 R. F.Lobo, M.Pan, I.Chan, H.-X.Li, R. C.Medrud, S. I.Zones, P. A.Crozier, M. E.Davis, Science 1993, 262, 1543–1546.17829383 [PubMed]

7 S.Bhanumati, P.As hkenazi, S.Migdal, D.Ginsburg, Helv. Chim. Acta 1983, 66, 2703–2706.

8 G.Kubiak, J. M.Cook, U.Weiss, J. Org. Chem.1984, 49, 561–564.

9 R. D.Bach, J. Org. Chem.1968, 33, 1647–1649.

10 M. E.Davis, S. I.Zones in Synthesis of Porous Materials: Zeolites, Clays and Nanostructures, Marcel Dekker, New York, 1997, pp. 1–34.

11 U. W.Arndt, A. J.Wonacott, Rotation Method in Crystallography, North-Holland, Amsterdam, 1977.

12 I.Nederlof, E.van Genderen, Y.-W.Li, J. P.Abrahams, Acta Crystallogr. Sect. D 2013, 69, 1223–1230.23793148 [OpenAIRE] [PubMed]

13 M. O.Cichocka, J.Ångström, B.Wang, X.Zou, S.Smeets, J. Appl. Crystallogr.2018, 51, 1652–1661.30546290 [OpenAIRE] [PubMed]

14 S. Smeets, B. Wang, M. O. Cichocka, J. Ångström, W. Wan, Instamatic 1.0, Zenodo, https://dx.doi.org/10.5281/zenodo.1090388, 2018.

15 W.Kabsch, Acta Crystallogr. Sect. D 2010, 66, 125–132.20124692 [PubMed]

36 references, page 1 of 3
Abstract
The high‐silica zeolite SSZ‐27 was synthesized using one of the isomers of the organic structure‐directing agent that is known to produce the large‐pore zeolite SSZ‐26 (CON). The structure of the as‐synthesized form was solved using multi‐crystal electron diffraction data. Data were collected on eighteen crystals, and to obtain a high‐quality and complete data set for structure refinement, hierarchical cluster analysis was employed to select the data sets most suitable for merging. The framework structure of SSZ‐27 can be described as a combination of two types of cavities, one of which is shaped like a heart. The cavities are connected through shared 8‐ring win...
Subjects
free text keywords: General Chemistry, Catalysis, Research Article, Research Articles, Zeolites, electron diffraction, SSZ-27, structure determination, structure-directing agents (SDAs), zeolites; electron diffraction; SSZ-27; structure determination; structure-directing agents (SDAs), General Medicine, multicrystal electron diffraction, structure refinement, zeolites, SSZ-27, hierarchical cluster analysis, heart shaped cavity, Communication channel, Materials science, Zeolite, Electron diffraction, Complete data, Crystal, Molecular physics, Hierarchical clustering, Merge (version control), Data set
Communities
  • Social Science and Humanities
Funded by
NSF| Acquisition of Solid-State NMR Equipment
Project
  • Funder: National Science Foundation (NSF)
  • Project Code: 9724240
  • Funding stream: Directorate for Mathematical & Physical Sciences | Division of Materials Research
,
SNSF| Development of serial electron crystallography methodology for quantitative phase analysis
Project
  • Funder: Swiss National Science Foundation (SNSF)
  • Project Code: P300P2_177761
  • Funding stream: Careers;Fellowships | Advanced Postdoc.Mobility
,
SNSF| Development of serial crystallography methods for structure solution of polycrystalline materials using electron diffraction
Project
  • Funder: Swiss National Science Foundation (SNSF)
  • Project Code: P2EZP2_165282
  • Funding stream: Careers;Fellowships | Early Postdoc.Mobility
Download fromView all 8 versions
Open Access
NARCIS
Article . 2019
Provider: NARCIS
Open Access
Angewandte Chemie
Article . 2019
Provider: Crossref
Open Access
Caltech Authors
Article . 2019
36 references, page 1 of 3

1 S. I.Zones, Microporous Mesoporous Mater.2011, 144, 1–8.

2 F.Gao, J. H.Kwak, J.Szanyi, C. H. F.Peden, Top. Catal.2013, 56, 1441–1459.

3 C.Baerlocher, L. B.McCusker, D. H.Olson, Atlas of Zeolite Framework Types, Elsevier, Amsterdam, 2007.

4 S. I.Zones, M. M.Olmstead, D. S.Santilli, J. Am. Chem. Soc.1992, 114, 4195–4201.

5 S. I.Zones, Microporous Mater.1994, 2, 281–287.

6 R. F.Lobo, M.Pan, I.Chan, H.-X.Li, R. C.Medrud, S. I.Zones, P. A.Crozier, M. E.Davis, Science 1993, 262, 1543–1546.17829383 [PubMed]

7 S.Bhanumati, P.As hkenazi, S.Migdal, D.Ginsburg, Helv. Chim. Acta 1983, 66, 2703–2706.

8 G.Kubiak, J. M.Cook, U.Weiss, J. Org. Chem.1984, 49, 561–564.

9 R. D.Bach, J. Org. Chem.1968, 33, 1647–1649.

10 M. E.Davis, S. I.Zones in Synthesis of Porous Materials: Zeolites, Clays and Nanostructures, Marcel Dekker, New York, 1997, pp. 1–34.

11 U. W.Arndt, A. J.Wonacott, Rotation Method in Crystallography, North-Holland, Amsterdam, 1977.

12 I.Nederlof, E.van Genderen, Y.-W.Li, J. P.Abrahams, Acta Crystallogr. Sect. D 2013, 69, 1223–1230.23793148 [OpenAIRE] [PubMed]

13 M. O.Cichocka, J.Ångström, B.Wang, X.Zou, S.Smeets, J. Appl. Crystallogr.2018, 51, 1652–1661.30546290 [OpenAIRE] [PubMed]

14 S. Smeets, B. Wang, M. O. Cichocka, J. Ångström, W. Wan, Instamatic 1.0, Zenodo, https://dx.doi.org/10.5281/zenodo.1090388, 2018.

15 W.Kabsch, Acta Crystallogr. Sect. D 2010, 66, 125–132.20124692 [PubMed]

36 references, page 1 of 3
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