publication . Thesis . 2014

N-heterocyclic carbene gold hydroxide complexes as bond activation reagents

Dupuy, Stéphanie;
Open Access English
  • Published: 01 Nov 2014
  • Publisher: University of St Andrews
  • Country: United States
Abstract
Although known since the 1930s, organogold chemistry has been dormant until recently, primarily due to preconceptions about the inertness of gold in transformations. However, this last decade has witnessed the emergence of a Golden Age with the development of a wealth of reports on gold in a plethora of reactions. In recent years, the drive for more atom- and step-economical and environmentally friendly reactions has become a field of intense research. In our on-going research on well-defined transition metal complexes bearing NHC ligands, our group recently discovered a new gold(I) hydroxide complex [Au(OH)(IPr)] (1a) that can be easily synthesised from the chl...
Subjects
free text keywords: QD412.A9D8, Organogold compounds--Analysis, Carbenes (Methylene compounds), Complex compounds
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