Carbonate binding to copper(II) in solution: mixed-ligand complex formation and its application to the isolation and separation of the three isomers of [Cu(bpp)(H2O)][ClO4]2 [bpp = 2,6-bis(pyrrolidin-2-yl)pyridine]

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Bernauer, Klaus; Godefroy, Isabelle; Cabort, Amel; Guicher, Nathalie; Stoeckli-Evans, Helen; Süss-Fink, Georg;

The binding of the carbonate anion to [Cu(<i>meso</i>-bpp)(H<sub>2</sub>O)]<sup>2+</sup> and <i>rac</i>-[Cu(bpp)(H<sub>2</sub>O)]<sup>2+</sup> [bpp = 2,6-bis(pyrrolidin-2-yl)pyridine] in aqueous solution has been investigated. Formation constants of the carbonato comple... View more
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