From simple rings to one-dimensional channels with calix[8]arenes, water clusters, and alkali metal ions

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Bergougnant, Rémi D.; Robin, Adeline Y.; Fromm, Katharina M.;

The macrocycle 4-<i>tert</i>-butylcalix[8]arene (L) was reacted with alkali metal carbonates (Li₂CO₃, Na₂CO₃, K₂CO₃, Rb₂CO₃, and Cs₂CO₃) at the interface of a biphasic THF/water system. Needle-like crystals with a general formula [A<i><sub>x</sub></i>(4-<i>tert</i>-buty... View more
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