publication . Article . 2002

ORGANOMETALLIC IRON(II) COMPLEXES CONTAINING P-SUBSTITUTED ACETOPHENONE-ARYLHYDRAZONE LIGANDS

Manzur,Carolina; Millán,Lorena; Figueroa,Walter; Hamon,Jean-René; Mata,Jose A.; Carrillo,David;
Open Access
  • Published: 01 Dec 2002 Journal: Boletín de la Sociedad Chilena de Química, volume 47 (eissn: 0366-1644, Copyright policy)
  • Publisher: SciELO Comision Nacional de Investigacion Cientifica Y Tecnologica (CONICYT)
Abstract
A series of twelve new organometallic acetophenone-hydrazone complexes of general formula [(h 5-Cp)Fe(h 6-o-RC6H4)-NHN=CMe-C6H4-p-R’]+PF6- (Cp= C5H5; R,R’=H,Me, [5]+PF6-; H,MeO, [6]+PF6-; H,NMe2, [7]+PF6-; Me,Me, [8]+PF6-; Me,MeO, [9]+PF6-; Me,NMe2, [10]+PF6-; MeO,Me, [11]+PF6-; MeO,MeO, [12]+PF6-; MeO,NMe2, [13]+PF6-; Cl,Me, [14]+PF6-; Cl,MeO, [15]+PF6-; Cl,NMe2, [16]+PF6-) has been prepared by reaction between their corresponding organometallic hydrazine precursors [(h 5-Cp)Fe(h 6-o-RC6H4)-NHNH2]+PF6- (R=H, [1]+PF6-; Me, [2]+PF6-; MeO, [3]+PF6-; Cl, [4]+PF6-, and aromatic ketones of the type MeC(=O)C6H4-p-R’ (R’=Me, MeO, NMe2) in refluxing ethanol containing c...
Subjects
free text keywords: Mixed sandwiches, organometallic arylhydrazone, acetophenome-arylhydrazone, dipolar chomophores, X-ray structure, Sandwich mixtos, arilhidrozonas organometálicas, arilhidrozonasde acetofenomas, crómosforos, estructuras de rayos-X, General Chemistry, Medicinal chemistry, Organic chemistry, Chemistry, Acetophenone, chemistry.chemical_compound, Ligand
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publication . Article . 2002

ORGANOMETALLIC IRON(II) COMPLEXES CONTAINING P-SUBSTITUTED ACETOPHENONE-ARYLHYDRAZONE LIGANDS

Manzur,Carolina; Millán,Lorena; Figueroa,Walter; Hamon,Jean-René; Mata,Jose A.; Carrillo,David;