Sequential Enzymatic Conversion of α‐Angelica Lactone to γ‐Valerolactone through Hydride‐Independent C=C Bond Isomerization

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Turrini, Nikolaus G.; Eger, Elisabeth; Reiter, Tamara C.; Faber, Kurt; Hall, Mélanie;

Abstract A case of hydride‐independent reaction catalyzed by flavin‐dependent ene‐reductases from the Old Yellow Enzyme (OYE) family was identified. α‐Angelica lactone was isomerized to the conjugated β‐isomer in a nicotinamide‐free and hydride‐independent process. The ... View more
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