Origins of 1,6-Stereoinduction in Torquoselective 6π Electrocyclizations

Other literature type English OPEN
Patel, Ashay; Barcan, Gregg A.; Kwon, Ohyun; Houk, K. N.;

A novel stereoselective electrocyclization developed for the total synthesis of reserpine has been explored by both experiment and theory. A stereocenter 6 atoms away from the newly forming chiral center is responsible for the diastereoselectivity of the ring closure. T... View more
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