publication . Doctoral thesis . 2008

Synthesis and study of new oxazoline-based ligands

Tilliet, Mélanie;
Open Access English
  • Published: 01 Jan 2008
  • Publisher: KTH, Organisk kemi
  • Country: Sweden
Abstract
This thesis deals with the study of oxazoline-based ligands in metal-catalyzed asymmetric reactions. The first part describes the synthesis of six new bifunctinal pyridine-bis(oxazoline) ligands and their applications in asymmetric metal-catalysis. These ligands, in addition to a Lewis acid coordination site, are equipped with a Lewis basic part in the 4-position of the oxazoline rings. Dual activation by means of this system was probed in cyanide addition to aldehydes. The second part is concerned with the synthesis of two pyridine-bis(oxazoline) ligands bearing bulky triazole groups in the 4-position of the oxazoline rings and a macrocyclic ligand consisting o...
Read more
Subjects
free text keywords: organic chemistry, Organisk kemi
Related Organizations
Download from
Publikationer från KTH
Doctoral thesis . 2008
Provider: Publikationer från KTH

R R 44

Powered by OpenAIRE Research Graph
Any information missing or wrong?Report an Issue