publication . Doctoral thesis . 2008

Synthesis and study of new oxazoline-based ligands

Tilliet, Mélanie;
Open Access English
  • Published: 01 Jan 2008
  • Publisher: KTH, Organisk kemi
  • Country: Sweden
Abstract
This thesis deals with the study of oxazoline-based ligands in metal-catalyzed asymmetric reactions. The first part describes the synthesis of six new bifunctinal pyridine-bis(oxazoline) ligands and their applications in asymmetric metal-catalysis. These ligands, in addition to a Lewis acid coordination site, are equipped with a Lewis basic part in the 4-position of the oxazoline rings. Dual activation by means of this system was probed in cyanide addition to aldehydes. The second part is concerned with the synthesis of two pyridine-bis(oxazoline) ligands bearing bulky triazole groups in the 4-position of the oxazoline rings and a macrocyclic ligand consisting o...
Subjects
free text keywords: organic chemistry, Organisk kemi
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