Steric control of reactivity: formation of oximes, benzodiazepinone N-oxides and isoxazoloquinolinones

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Heaney, Frances; Bourke, Sharon; Cunningham, Desmond; McArdle, Patrick;

Reaction of the alkenyl carbonyl compounds 1 with hydroxylamine can lead to the formation of the oximes 2, the benzodiazepinone N-oxides 3 or the isoxazoloquinolinones 5. The product(s) of reaction are shown to depend on the electronic nature of the terminal olefinic su... View more
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