Synthesis and reactivity of a PCcarbeneP cobalt(I) complex: the missing link in the cobalt PXP pincer series (X = B, C, N)

Article English OPEN
Sung, Simon; Wang, Qingyang; Krämer, Tobias; Young, Rowan D;
  • Publisher: Royal Society of Chemistry
  • Related identifiers: doi: 10.1039/c8sc02782j
  • Subject:
    mesheuropmc: inorganic chemicals

We report the first example of a cobalt PCcarbeneP pincer complex (1) featuring a central alkylidene carbon donor accessed through the dehydration of an alcoholic POP proligand. Complex 1 shares bonding similarities with cobalt PBP and PNP pincer complexes where the don... View more
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