Experimental study of the structure of rich premixed 1,3-butadiene/CH4/O2/Ar flame.

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Gueniche , Hadj-Ali ; Glaude , Pierre-Alexandre ; Fournet , René ; Battin-Leclerc , Frédérique (2006)
  • Publisher: HAL CCSD
  • Subject: [ PHYS.PHYS.PHYS-CHEM-PH ] Physics [physics]/Physics [physics]/Chemical Physics [physics.chem-ph]

traduit de Fizika Goreniya I Vzryva, 2006, 42, 89-95.; The structure of a laminar rich premixed 1,3-C4H6/CH4/O2/Ar flame have been investigated. 1,3-Butadiene, methane, oxygen and argon mole fractions are 0.033; 0.2073; 0.3315, and 0.4280, respectively, for an equivalent ratio of 1.80. The flame has been stabilized on a burner at a pressure of 6.7 kPa (50 Torr). The concentration profiles of stable species were measured by gas chromatography after sampling with a quartz probe. Quantified species included carbon monoxide and dioxide, methane, oxygen, hydrogen, ethane, ethylene, acetylene, propyne, allene, propene, cyclopropane, 1,3-butadiene, butenes, 1-butyne, vinylacetylene, diacetylene, C5 compounds, benzene, and toluene. The temperature was measured thanks to a thermocouple in PtRh (6%)-PtRh (30%) settled inside the enclosure and ranged from 900 K close to the burner up to 2100 K.
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