publication . Article . 2014

Synergistic Stereoselective Organocatalysis with Indium(III) Salts

Andrea Gualandi; Luca Mengozzi; Claire Margaret Wilson; Pier Giorgio Cozzi;
Closed Access English
  • Published: 25 Mar 2014
  • Country: Italy
Abstract
The compatibility of indium(III) Lewis acids with water and amines allows their employment in synergistic and cooperative catalysis. Stereoselective organocatalytic S(N)1-type reactions, in which carbenium ions are generated, are promoted by the presence of indium salts. The peculiar properties of indium salts can be exploited in organocatalysis for the design of water-compatible, benign, green processes. The development of such indium(III)-promoted organocatalytic procedures is the focus of our recent research, a summary of which is presented in this article. The compatibility of indium(III) Lewis acids with water and amines allows their employment in synergist...
Subjects
Medical Subject Headings: digestive, oral, and skin physiologyrespiratory systeminorganic chemicalscirculatory and respiratory physiology
free text keywords: organocatalysis, stereoselective, amine catalysis, enamine-mediated catalysis, Indium, III, indium (III), Organic Chemistry, Catalysis, Chemistry, Stereoselectivity, chemistry.chemical_element, Lewis acids and bases, Allylic rearrangement
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publication . Article . 2014

Synergistic Stereoselective Organocatalysis with Indium(III) Salts

Andrea Gualandi; Luca Mengozzi; Claire Margaret Wilson; Pier Giorgio Cozzi;