Synergistic Stereoselective Organocatalysis with Indium(III) Salts

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Gualandi, Andrea; Mengozzi, Luca; Wilson, Claire Margaret; Cozzi, Pier Giorgio;
  • Identifiers: doi: 10.1055/s-0033-1341022
  • Subject: organocatalysis | amine catalysis | enamine-mediated catalysis | Indium | III | stereoselective | indium (III)
    mesheuropmc: respiratory system | inorganic chemicals | circulatory and respiratory physiology | digestive, oral, and skin physiology

The compatibility of indium(III) Lewis acids with water and amines allows their employment in synergistic and cooperative catalysis. Stereoselective organocatalytic S(N)1-type reactions, in which carbenium ions are generated, are promoted by the presence of indium salts... View more
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