A rectangular Ni-Fe cluster with unusual cyanide bridges

Article English OPEN
Krüger, Christoph; Sato, Hiroki; Matsumoto, Takuto; Shiga, Takuya; Newton, Graham N.; Renz, Franz; Oshio, Hiroki;
  • Publisher: Cambridge : Royal Society of Chemistry
  • Related identifiers: doi: 10.15488/2156, doi: 10.1039/c2dt31152f
  • Subject: Ferro-magnetic interactions | Nickel | Nickel irons | Cyanides | Iron compounds | Metal ions | Nickel ions | Cyanide bridge | Synthesis (chemical) | Capping ligands | Iron ions | Iron complex
    • ddc: ddc:540
    mesheuropmc: inorganic chemicals

An asymmetric polycyanide iron complex, K2[Fe III(L1)(CN)4](MeOH) (HL1 = 2,2′-(1H-pyrazole-3,5- diyl)bis-pyridine), was synthesized and its complexation compatibility with nickel ions was examined. Two kinds of enantiomeric nickel-iron squares were obtained in the prese... View more
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