publication . Article . 2006

An EPR Monitoring of Isomerism and coordination sphere dynamics in five-coordinated pincer nickel complexes

Kozhanov, K.; Bubnov, M.; Cherkasov, V.; Fukin, G.; Vavilina, N.; Efremova, L.; Abakumov, G.;
Open Access Russian
  • Published: 01 Jan 2006
  • Publisher: Федеральное государственное автономное образовательное учреждение высшего образования «Казанский (Приволжский) федеральный университет»
Abstract
A number of five-coordinated paramagnetic pincer nickel complexes have been obtained and investigated by X-band EPR spectroscopy. In general, these complexes can exist in solution as a pair of interconverting structure isomers. Activation parameters of this interconversion were estimated for several complexes.
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