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Комплексные соединения гидроксипроизводного динитробензофуроксана. Часть 1. Спектральные исследования комплексов на основе трихлорида родия и динатриевого комплекса 4,6-динитро-1-оксобенз[6,5-c]-2,1,3-оксадиазолдиола-5,7

Комплексные соединения гидроксипроизводного динитробензофуроксана. Часть 1. Спектральные исследования комплексов на основе трихлорида родия и динатриевого комплекса 4,6-динитро-1-оксобенз[6,5-c]-2,1,3-оксадиазолдиола-5,7

Abstract

С помощью ИК спектроскопии установлено, что при комплексообразовании трихлорида родия с 4,6-динитро-1-оксобенз[6,5c ]-2,1,3-оксадиазолдиол-5,7 в водной среде и водно-ацетоновой среде фураксановый цикл сохраняется; молекулы лиганда координируются к иону родия с помощью атома азота фураксанового цикла и одним из атомов кислорода нитрогруппы. В комплексах присутствуют терминальные ( Rh–Cl) и мостиковые ( Rh–Cl–Rh) связи ; координированная и кристаллизационная вода; ( π-π ) взаимодействие арильного цикла лиганда с ионами родия. В состав комплексов входит несколько молекул лиганда, имеющих разную ориентацию в пространстве. Установлена полиядерно-полилигандная структура, обеспечивающая достаточно высокую термическую устойчивость.

By IR spectroscopy indicated that the complexation of rhodium trichloride with 4,6-dinitro-1-oxobenz[6,5-c] -2,1,3-oxodiazoldiol-5, 7 in an aqueous medium and a water-acetone medium furaxane cycle is stored; molecule ligand coordinated to the rhodium ion by the furaxane cycle’s nitrogen atom and one oxygen atom from nitrogroup. In the complexes are present terminal ( Rh-Cl ) and bridging ( Rh-Cl-Rh ) binds; coordinated and crystal water; ( π π ) interaction rhodium ions with ligand’s aryl ring. The complex consists of several ligand molecules with different orientations in space. Polyligand-polynuclear structure was established and provided high thermal stability.

Keywords

ГИДРОКСИПРОИЗВОДНЫЕ ДИНИТРОБЕНЗОФУРАКСАНА, ДИНАТРИЕВЫЙ КОМПЛЕКС 4, 6-ДИНИТРО-1-ОКСОБЕНЗ[6, 5-C]-2, 3-ОКСАДИАЗОЛДИОЛА-5, ТРИХЛОРИД РОДИЯ, КОМПЛЕКСООБРАЗОВАНИЕ, СИНТЕЗ, ВОДНАЯ СРЕДА, ВОДНО-АЦЕТОНОВАЯ СРЕДА, СПЕКТРАЛЬНЫЕ ИССЛЕДОВАНИЯ, 6-DINITROО-1-OXOBENZ[6

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
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