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Поликапроамидные системы с полифторированными фрагментами

Поликапроамидные системы с полифторированными фрагментами

Abstract

Рассмотрены методы получения фторсодержащего поликапроамида и поликапроамидных систем с полифторированными фрагментами на стадии синтеза полимера и в процессе его переработки. Проанализировано влияние малых концентраций полифторированных компонентов (0,02-0,25 %масс.) на процесс формирования кристаллической и аморфных фаз в поликапромидных системах, который в существенной степени определяет светостабильность и термическую стойкость, высокую износостойкость, устойчивость к воздействию химических сред и высоких температур поликапроамидных материалов. Библиография 115 ссылок.

Methods for production of fluorine containing polycaproamide and polycaproamide systems with polyfluorinated fragments, based on introduction of the above mentioned fragments during the polymer synthesis and the process of fibers production, were examined. The influence of microquantities of polyfluorinated components (0,02-0,25 % mass.) on the process of formation of the crystal and amorphous phases in polycaproamide systems, which defines light-, thermo-, threadbare stability, stability in aggressive medium and high temperatures of polycaproamide materials, was analyzed.

Keywords

ПОЛИКАПРОАМИД, ПОЛИКАПРОАМИДНЫЕ СИСТЕМЫ, ПОЛИФТОРИРОВАННЫЕ ФРАГМЕНТЫ, КРИСТАЛЛИЧЕСКАЯ ƒ-ФАЗА, АМОРФНАЯ ФАЗА, ГИДРОЛИТИЧЕСКАЯ ПОЛИМЕРИЗАЦИЯ, ƒ-КАПРОЛАКТАМ, ВОЛОКНО, ТЕРМОСТАБИЛЬНОСТЬ, СВЕТОСТАБИЛЬНОСТЬ, ИЗНОСОСТОЙКОСТЬ, ФОТООКИСЛЕНИЕ, ПМР-СПЕКТРЫ, ДИФРАКТОГРАММЫ, ВОДОРОДНЫЕ СВЯЗИ, КОНФОРМАЦИЯ, ТРИБОМОДИФИКАТОРЫ, CRYSTAL ƒ-PHASE, ƒ-CAPROLACTAM

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
Average
gold