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К вопросу о природе ферромагнетизма в оксидных полупроводниках, легированных 3d-элементами

К вопросу о природе ферромагнетизма в оксидных полупроводниках, легированных 3d-элементами

Abstract

TiO 2) различными 3d-примесями.The origin and mechanisms of ferromagnetism in the new class of magnetic materials, oxide-diluted magnetic semiconductors (O-DMS), are examined in the framework of the Stoner\,–\,Anderson model. Within the Green function formalism, a condition (the Stoner criterion) for nucleation of ferromagnetism is obtained for itinerant electrons in the narrow defect (vacancy) band, and an additional contribution caused by the interaction with 3d magnetic ions is derived. The ``trigger'' character of the transition to the ferromagnetic state in O-DMS is discussed in its dependence on the type and concentration of 3d magnetic impurity dopant. The results of the calculations are compared with the experimental data for the spontaneous magnetic moment in semiconducting titanium dioxide (TiO 2) doped with 3d magnetic ions and containing various concentrations of oxygen vacancies.

В рамках объединенной модели Стонера – Андерсона обсуждаются природа ферромагнетизма и механизмы возникновения дальнего магнитного порядка в новом классе магнитных материалов: магниторазбавленных оксидных полупроводниках. С использованием техники функций Грина найдены условия (критерий Стонера) возникновения ферромагнетизма в оксидном полупроводнике за счет спиновой поляризации электронов, коллективизированных в узкой дефектной (вакансионной) зоне, и рассчитан дополнительный вклад, обусловленный взаимодействием последних с магнитными ионами 3d-элементов. Дискутируется “спусковой” характер механизма магнитного упорядочения в оксидном полупроводнике и его зависимость от концентрации и химического типа легирующей магнитной примеси. Результаты, вытекающие из модели, сопоставляются с экспериментальными данными о легировании полупроводникового диоксида титана (

Keywords

МАГНИТОРАЗБАВЛЕННЫЕ ОКСИДНЫЕ ПОЛУПРОВОДНИКИ, ФЕРРОМАГНЕТИЗМ, КИСЛОРОДНЫЕ ВАКАНСИИ, УЗКИЕ ДЕФЕКТНЫЕ ЗОНЫ, КРИТЕРИЙ СТОНЕРА

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
Average
gold