publication . Article . Other literature type . 2019

A π‐Conjugated, Covalent Phosphinine Framework

Huang, Jieyang; Tarábek, Ján; Kulkarni, Ranjit; Wang, Cui; Dračínský, Martin; Smales, Glen J.; Tian, Yu; Ren, Shijie; Pauw, Brian R.; Resch‐Genger, Ute; ...
Open Access English
  • Published: 13 Aug 2019 Journal: Chemistry (Weinheim an Der Bergstrasse, Germany), volume 25, issue 53, pages 12,342-12,348 (issn: 0947-6539, eissn: 1521-3765, Copyright policy)
  • Publisher: John Wiley and Sons Inc.
  • Country: Germany
Abstract
Phosphinine in π: For the first time since its synthesis in 1966, the six‐membered phosphinine ring is incorporated into a π‐conjugated polymer. The phosphinine‐based framework (CPF‐1) has a high concentration of paramagnetic species, high thermal stability, green fluorescence, and shows activity in photocatalytic water splitting.
Subjects
free text keywords: 540 Chemie und zugeordnete Wissenschaften, 660 Chemische Verfahrenstechnik, Full Paper, Full Papers, π‐Conjugated Polymers, fluorescence, phosphinine, polymers, Suzuki–Miyaura coupling, π-conjugated frameworks, 500 Naturwissenschaften und Mathematik::540 Chemie::540 Chemie und zugeordnete Wissenschaften, conjugated microporous polymer, photocatalysis, heteroatom, ddc:540, ddc:660, General Chemistry, Polymer chemistry, Organic chemistry, Covalent bond, Conjugated system, Polymer, chemistry.chemical_classification, chemistry
Funded by
EC| BEGMAT
Project
BEGMAT
Layered functional materials - beyond 'graphene'
  • Funder: European Commission (EC)
  • Project Code: 678462
  • Funding stream: H2020 | ERC | ERC-STG
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publication . Article . Other literature type . 2019

A π‐Conjugated, Covalent Phosphinine Framework

Huang, Jieyang; Tarábek, Ján; Kulkarni, Ranjit; Wang, Cui; Dračínský, Martin; Smales, Glen J.; Tian, Yu; Ren, Shijie; Pauw, Brian R.; Resch‐Genger, Ute; ...